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my brother is just learning the game and his stats are 32/16/2. He is winning a decent amount at .5/1 over 10K hands (something like 1.9BB/100) I am trying to get him to read 2+2 and to tighten up, but so far unsuccessful.

2K hands really can't tell you much.

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I would love to be able to play 32/16 and win. Maybe he is a natural hand reader.