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The 'duty' is actually the 7% GST.
Used or new makes no difference - value does.
If you could get them mailed Canada Post brokerage fee is $5.(plus the GST)
Couriers charge a bunch because of the extra handling involved in clearing customs and collecting the tax FOR CCRA.
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PSO only ships UPS.
But ya, poker chips are duty free (as in no additional tax beyond GST) regardless of where they're made, so you're only subject to the 7% GST.
Scroll down to the post by dad604 for details on clearing customs yourself. He's even got the tariff # for the chips and cards.
http://www.pokersourceonline.com/forum/v...sc&start=15