Having used Paypal for non poker things the last few years, I have to say that I've had a much better experience with Neteller. That a google search *doesn't* yield netellersucks.com and netellerwarning.com is probably a good sign.

I hooked Neteller up to my checking account since I don't maintain a large balance on it. If you really want to be safe, open a new bank account just for poker / Neteller.