I would suggest getting a case without a power supply, and buying a separate power supply. Most supplies that come with the case are not very good. The power supply is very important, and you don't want to ruin good hardware with a crappy supply that craps out. OCZ and Seasonic are excellent brands IMO. Get a good 400w+ supply.
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I am pretty sure that I don't need that nice of a motherboard, so if you have other suggestions, I'm listening.
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The motherboard is the heart of your system. It's worth it to invest in a decent board. Your choice is good. Another suggestion is the
MSI K8N Neo4 SLI board. AMD compatible, and an excellent board with SLI support for a regular user. The DFI boards are better for overclocking, but MSI is the best IMO for regular users. It's also only $127, and the sound card on it is the best onboard sound.
Finally, I think a 3500 Venice is overkill for your purposes. Just get the Venice 3000 , which is much cheaper and the performance difference won't be huge. You can always learn to overclock it later if you need to (you won't).
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Your other selections look fine. Corsair ram is good, and Seagates are solid. Finally, you might have to invest in a new CPU fan and heatsink. I'm not sure how good the fans that come with the venice are. GOod luck.
Edit: If you want 2 monitor support, just buy a regular card (1 DVI, 1 analog video) or a dual DVI card (more expensive). No point in buying two cards unless you want to set up SLI support for games.